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Hextech is a portmanteau of hex and technology, they are any mechanical device. Both Hextech and Steampunk are what fuel the machines of progress in both Piltover and Zaun. Rather than heated steam and other ways of fuel, liquified magic is the fuel. Both Zaun and Piltover are the most tuned into this magic, but both have vastly differing motives.
Hextech could refer to the following in League of Legends: